Cobaloxime Catalyst Enables Regiodivergent Hydrogen Atom Transfer for Alkenyl and Allylic Carbamoylation

A new catalytic system utilizing cobaloxime has been developed for a regiodivergent hydrogen atom transfer process. This method efficiently achieves the carbamoylation of alkenes and allylic positions, even with branched substrates. The catalyst allows for precise control over the reaction's regioselectivity, leading to desired product formation. This advancement offers a valuable tool for synthetic chemists seeking to functionalize olefins in a controlled manner. The study highlights the versatility of cobaloxime catalysts in promoting complex organic transformations. These findings could lead to improved synthesis strategies for various organic molecules.

This discovery offers a more controlled and efficient method for synthesizing complex organic molecules, advancing the field of synthetic chemistry.